mono ethylene glycol properties

Ethylene Glycol: The molecular weight of ethylene glycol is about 62.07 g/mol. Melting point – 12.9 °C (8.8 °F; 260.2 K), Boiling point – 197.3 °C (387.1 °F; 470.4 K), Solubility – Soluble in most organic solvents. Ethylene Glycol: HOCH 2CH 2OH CAS Registry Number: 107-21-1 Synonyms: 1, 2-Ethanediol Glycol EG Monoethylene glycol Ethylene glycol is produced from ethylene, via the … It is a water-soluble liq… Forecasts suggest that by 2015, demand could be above 28 million tonnes per year. Shell opened one of the world’s largest MEG plants in November 2009 at its integrated refinery and petrochemicals hub in Singapore. ... PROPERTIES 9.1 Physical State at 15° C and 1 atm: Liquid 9.2 … Increased use of ethylene glycol in polyester fibers due to its mechanical and chemical properties especially in Asian-Pacific regions. The gauche conformer of mono ethylene glycol has been considered for our study. Ethylene glycol (EG) is an important organic compound and chemical intermediate used in a large number of industrial processes (e.g. The ethylene glycol family's solvency properties are useful in Custom formulation of paints, dyes, … 25% of MEG is used in polyethylene terephthalate - or PET - packaging and bottles. Its chemical formula is C 2 H 4 (OH) 2. Rapid urbanization and changing the lifestyle of customers especially in emerging countries. More information on Shell’s MEG and ethylene oxide process technology, including OMEGA, is on a separate factsheet. As it has a low freezing and high boiling point, it proves to be a great component in the manufacturing industry. Note: global data sourced from PCI Xylenes and Polyesters Ltd, Industrial Lubricants and Oils for Business, New Energies: building a lower-carbon power business, Sustainability reporting and performance data, Shell Rimula Truck & Heavy-duty Engine Oils, More and cleaner energy solutions for your business, Our home energy offer for households in Great Britain, Purchase order general terms and conditions, Shell invoicing channels and invoice requirements, Electronic signature data privacy statement, Health, Security, Safety and the Environment, Subscribe to Shell Catalysts & Technologies, View Industrial Lubricants and Oils for Business, Flightpath: exploring the future of aviation, The benefits of chemicals in everyday life, Shell FuelSave Diesel and Shell Diesel Extra, Shell Fuel Oil Plus and Shell Fuel Oil Extra, Shell Electronic Vendor Managed Inventory, HSSE & Social Performance Commitment and Policy. TOXICITY. Mono Ethylene Glycol (MEG) Cas No 107-21-1. Anti-freeze for portable water systems in seasonal homes & recreational water systems. Based on application market can be segmented into the fiber, polyethylene terephthalate (PET), film, anti-freeze and other industrial applications. Olivia Fandiño, Alfonso S. Pensado, Luis Lugo, … Medium for suspending conductive salt in electrolytic capacitors. Ethylene glycol is a chemical compound that has an alcohol with two -OH groups. What are the Advantages & Disadvantages of using Mono-Ethylene Glycol? It is completely miscible with water and many organic liquids. Synonyms :1,2-Ethanediol; Monoethylene glycol; MEG; EG . The difference between Propylene Glycol and Ethylene Glycol in antifreeze comes down to both toxicity levels and efficiency of performance. ETHYLENE GLYCOL EGL CAUTIONARY RESPONSE INFORMATION Common Synonyms Thick liquid Colorless Odorless Sinks and mixes with water. (Monoethylene Glycol / MEG) Monoethylene glycol (MEG) in its pure form, it is an odorless, colorless, syrupy liquid with a sweet taste. Polyester and fleece fabrics, upholstery, carpets and pillows, as well as light and sturdy polyethylene terephthalate drink and food containers originate from ethylene glycol. International Journal of Thermophysics 2006, 27 (5) , 1354-1372. energy, plastics, automobiles, and chemicals).Indeed, owing to its unique properties and versatile commercial applications, a variety of chemical systems (e.g., catalytic and non-catalytic) have … End uses for MEG range from clothing and other textiles, through packaging to kitchenware, engine coolants and antifreeze. Stabilizer against gel formation. 55% of MEG is used to make polyester fibres. Glycols as a class are of a low order of toxicity (with the exception of oral toxicity). It is primarily used as a raw material to produce polyester fibers for the fabric industry, and polyethylene terephthalate resins (PET) used in … MEG is produced from ethylene via ethylene oxide, which in turn is hydrated by using either a thermal or catalytic production process. The plant has an annual capacity of 750,000 tonnes. Its sweet taste easily attracts kids and domestic animals which could be injurious to health. The density of ethylene glycol is higher than water - check the specific gravity (SG) table above, so the net impact on the heat transport capacity is reduced. Over the years Crystal India has also diversified its manufacturing unit by including a range of extensively used Glycol products, including Mono Ethylene Glycol, Di Ethylene Glycol, Tri Ethylene Glycol and Glycol Mix. It is an easily available and low-cost material. Formula: CH2OHCH2OH . Especially significant is resin f… Polyester and fleece fabrics, … In the formulation of food, drugs, and cosmetics. The humectant (water attracting) properties of MEG products also make them ideal for use in fibres treatment, paper, adhesives, printing inks, leather and cellophane. MEG based products are also used as coolants in Automobile antifreeze, resins, humectants MEG can be transported in Epoxy coated MS tankers. 1,2-Dihydroxyethane 1,2-Ethanediol Ethylene dihydrate Glycol Monoethylene glycol Call fire department. This chemistry permits ethylene glycol to act as an intermediate in a wide range of reactions. It is a colorless liquid which has a syrup-like consistency. What is mono ethylene glycol … End uses for MEG range from clothing and other textiles, through packaging to kitchenware, engine coolants and antifreeze. This solvent is soluble in water and holds hygroscopic properties, meaning it can attract hard water molecules. Product Name: Mono Ethylene Glycol (MEG) 99.8% . Glycols are widely used in … The common name ethylene glycol literally means “the glycol derived from ethylene.” It has a specific gravity of 1.115 and a flash point of 110 °C (closed cup). Temperature and Pressure Dependences of Thermophysical Properties of Some Ethylene Glycol Dimethyl Ethers from Ultrasonic Measurements. Mono-ethylene glycol - or MEG - is a vital ingredient for the production of polyester fibres and film, polyethylene terephthalate (PET) resins and engine coolants. Mono Ethylene Glycol Product Specifications Sr. No Property Unit Specifications 1 Appearance - Clear Colourless 2 MEG Content Wt % min 99.9 3 DEG Content Wt. TCCs Ethylene Glycol (MEG) is a toxic, colorless, practically odorless, low-volatility, low-viscosity, hygroscopic liquid. Page 1 of 8 MSDS- Mono Ethylene glycol Material Safety Data Sheet (MSDS) - Mono Ethylene glycol 1. A glycol is an alcohol with two hydroxyl groups on adjacent carbon atoms (a 1,2-diol). Shell is a leading global licenser of proprietary process technology for both catalytic/thermal and solely catalytic production of MEG. Ethylene glycol has properties which make it one of the most important forms of raw material for a variety of industrial process. Monoethylene glycol can be used as an intermediate in the production of solvents and resins or as a building block in PET to produce fibers. It is a colorless syrupy liquid, toxic and has a sweet taste. Ethylene Glycol – The Versatile Performer An interesting fact about MEG is that 21 million tons are manufactured around the … PHYSICAL AND CHEMICAL PROPERTIES. The end uses for ethylene glycol are numerous (See Table 1). MEG is the raw material used in the production of polyester fiber, PET resins, alkyds, and unsaturated polyesters. Mono Ethylene Glycol can be stored in stainless steel, aluminium, or lined drums, tank cars, or tank trucks. Shell’s MASTER process technology, which uses a catalyst to convert ethylene and oxygen into ethyelene oxide, followed by a thermal process, also produces smaller amounts of the co-products diethylene glycol (DEG) and triethylene glycol (TEG). Propylene glycol (IUPAC name: propane-1,2-diol) is a viscous, colorless liquid, which is nearly odorless but possesses a faintly sweet taste.Its chemical formula is CH 3 CH(OH)CH 2 OH. Diethylene glycol is used in the manufacture of unsaturated polyester resins, polyurethanes and plasticizers. Ethylene glycol, also called ethane-1,2-diol, the simplest member of the glycol family of organic compounds. Furthermore, MEG is commonly used as a raw material for antifreeze fluids. Deg C Deg C Max 196 199 1.0 … Shell’s new OMEGA catalytic process technology produces only ethylene glycol. DOI: 10.1007/s10765-006-0110-x. The optimized structures of mono, di, tri and tetra ethylene glycol are shown in Fig. It carries hygroscopic properties (readily attracts moisture from the air) and is miscible in all rations with water, alcohols, esters, ketones and amines. It is not regulated for transport on road, rail, air, or sea but it is classified as harmful, and is harmful if swallowed. Fluctuations in prices of raw materials and their availability such as crude oil and feedstock. An increased amount of investment in Research & Development of environment-friendly alternatives. Containing two alcohol groups, it is classed as a diol.It is miscible with a broad range of solvents, including water, acetone, and chloroform.In … Ethylene glycol is produced from ethylene, via the intermediate ethylene oxide. Increased demand of MEG from end-user industries including textile, automotive, paints & coatings, packaging etc. Annual output from the MEG plant in Singapore could produce over two million tonnes of polyester, enough to make 6.7 billion polyester shirts - more shirts than there are people in the world. Mono propylene glycol (with or without the space), is a viscous, colourless and odourless liquid. Glycol Ethers E series – excellent solvency, chemical stability, and compatibility with water and a number of organic solvents make them useful as chemical intermediates and in a broad array of applications, including cosmetics, cleaners and textiles. Monopropylene glycol (also known as propylene glycol, PG, propan1, 2diol and MPG) is a clear, colourless and viscous liquid with a characteristic odour and has the formula C3H8O2. The physical properties of ethylene glycol-water mixtures are therefore extremely important. 0.0 4 4 Specific Gravity @20/20 Deg C 1.1151 -1.1156 5 Distillation Range @ 760 mm H g IBP End Point 5 - 95 vol% range Deg C Min. Ethylene glycol, HOCH 2 CH 2 OH, is the simplest member of the glycol family. Mono-, di- and triethylene glycols are the first three members of a homologous series of dihydroxy alcohols. Monoethylene Glycol (MEG) Ethylene glycol is a colorless, practically odorless, low-volatility, low-viscosity, hygroscopic liquid. Cas no: 107-21-1. Based on the end-users market can be segmented into textile industry, packaging industry, plastic industry and others. Based on region market can be segmented into North America, Europe, APAC, Latin America and Middle East Africa. The hydroxyl groups on glycols undergo the usual alcohol chemistry, giving a wide variety of possible derivatives. Article details the physical properties of mono ethylene glycol (MEG), di-ethylene glycol (DEG), tri-ethylene glycol (TEG), and tetra-ethylene glycol (TREG); along with the Toxicity and Flammability requirements. What is Shell's Net Carbon Footprint ambition? 45% of the world’s MEG output is consumed in China. It has a similar structure to water which makes it miscible with the substance. Uses. Chemical Product and Company Identification Product Name : Mono Ethylene glycol Catalog Codes : SLE1072 CAS# : 107 -21 -1 RTECS : KW2975000 ... 9.Physical and Chemical Properties Physical state and … Synonym: 1,2-Dimethoxyethane, Dimethylglycol, Ethylene glycol dimethyl ether, Monoglyme, mono-Glyme Linear Formula: CH 3 OCH 2 CH 2 OCH 3 Molecular Weight: 90.12 The increased popularity of Bio-based MEG materials. It is an essential raw material for Polyester fibres and Polyethylene Terephthalate (PET) polymer. Mono Ethylene Glycol (MEG) is the most widely used chemical from the Glycol family. Mono Ethylene Glycol (MEG) is an essential component used as raw material in diverse industrial processes such as the manufacture resins, polyester, fibers and various types of films. MEG is a colourless, odourless liquid with a syrup-like consistency. Specific gravity at the same conditions is 1.077. Polyethylene Glycol: The molecular weight of polyethylene glycol depends on the value of “n” in its general formula. In China, MEG demand continues to grow at around 7% each year. Sustainability issues related to the material performance. There is a possible threat of combustion majorly in cars if the antifreeze leaks. Increased economic growth and rise in individual income level. It is completely miscible with water and many organic liquids. They are colourless, essentially … This material has good heat transfer capabilities. Ethylene Glycol: Ethylene glycol is mainly used for the manufacturing of polyester fibers and as an … Example - the specific heat of an ethylene glycol water solution 50% / 50% is 0.815 at 80 o F (26.7 o C). Mono Ethylene Glycol 9 PHYSICAL AND CHEMICAL PROPERTIES APPEARANCE Liquid COLOUR Colourless ODOUR Odourless SOLUBILITY Miscible with water. Mono-ethylene glycol - or MEG - is a vital ingredient for the production of polyester fibres and film, polyethylene terephthalate (PET) resins and engine coolants. Shell’s ambition to be a net-zero emissions energy business, Cutting carbon together, sector by sector, Natural Gas: providing more and cleaner energy, Putting Safety First in Shale Oil and Gas, Leveraging Technology in Shale Oil and Gas, Social and Environmental Responsibility in Shales, Chief Technology Officer and Chief Scientists, The role of technology in the energy transition, Another step towards a global electricity business, View New Energies: building a lower-carbon power business, Explore Shell’s Global Energy Resources database, Share your idea and transform the energy industry, Boosting local economies through entrepreneurship, Registration, Evaluation, Authorisation and Restriction of Chemicals (REACH), Preventing the facilitation of tax evasion, View Sustainability reporting and performance data, Voluntary reporting standards and ESG ratings, Investing in access to energy for communities, 4 tips to excel in a Shell face-to-face interview, 7 tips to prepare Students & Graduates for an online video Interview, 10 employees share their first week at Shell, 9 ways to help you find the right career path, Find a Job in the Shell Graduate Programme. ethylene glycol as an antifreeze is based on its ability to lower the freezing point when mixed with water. Dec 18, 2020. † Typical properties, not to be construed as specifications. Differences in their applications are due mainly to variations in physical properties such as viscosity, hygroscopicity and boiling point. a Ethylene glycol concentrations greater than 92% are not attainable with DOWTHERM 4000 fluid. Inappropriate disposal of MEG especially at runways of airports may harm the environment. †† Degree Brix is a measure of the sugar concentration in a fluid and is important in fermentation and syrups … ... due to the lower viscosity of ethylene glycol it possesses excellent … With a leading position in ethylene oxide/glycol technology and global logistics capability, we are well-placed to meet the needs of our global customers. 2,500 MTs of Crysol CU® 132 is annually manufactured, while the combined annual output of our Glycol … It is highly flammable and absorbs water rapidly. Diethylene glycol, CH2OHCH2OCH2CH2OH, is similar in properties to MEG (mono ethylene glycol), but DEG has a higher boiling point, viscosity, and specific gravity. Shell is a leading global producer of MEG, with world-scale plants in key markets, a global customer base and proven global logistics capability. Ethylene glycol is primarily used in antifreeze formulations (50%) and as a raw material in the manufacture of polyesters such as polyethylene terephthalate (PET) (40%). MEG is highly used in PET segment and increased usage of pet packaging in industries such as pharmaceutical, cosmetics, food & beverages etc. b Freezing points are below -60˚F (-51˚C). It offers a number of benefits to manufacturers such as: It has a similar structure to water which makes it miscible with the … % Max. Miscible with Acetone Alcohol BOILING POINT (°C)196 - 199 760 mm HgMELTING POINT (°C)-12 RELATIVE DENSITY1.115 @ 20 °c VAPOUR DENSITY (air=1)2.14 … Global MEG demand was around 21 million tonnes in 2010. Ethylene glycol possess far superior heat transfer properties whereas Propylene Glycol carries a very low toxicity. 1.The relative energy of ethylene glycol using B3LYP method with 6-311G, 6-311 + G, 6-311 + +G, 6-311 + +G*, SDD and TZVP basis sets is … In Automobile antifreeze, resins, humectants MEG can be transported in Epoxy coated tankers! Hydroxyl groups on glycols undergo the usual alcohol chemistry, giving a wide range reactions... The plant has an annual capacity of 750,000 tonnes as crude oil and feedstock member of the ’! Crude oil and feedstock, via the intermediate ethylene oxide process technology produces only ethylene glycol 9 physical chemical! Demand could be above 28 million tonnes in 2010 process technology produces only glycol... C deg C Max 196 199 1.0 … mono ethylene glycol ( MEG ) No. Mono Propylene glycol carries a very low toxicity of organic compounds on region market can be segmented into textile,. Coolants in Automobile antifreeze, resins, polyurethanes and plasticizers majorly in cars if antifreeze... On the value of “ n ” in its general formula, Latin and... America and Middle East Africa alkyds, and cosmetics industrial applications % are attainable! The Advantages & Disadvantages of using Mono-Ethylene glycol a possible threat of combustion majorly in cars the!, meaning it can attract hard water molecules SOLUBILITY miscible with the substance of mono di. S new OMEGA catalytic process technology produces only ethylene glycol in polyester fibers due to its and. Hard water molecules rapid urbanization and changing the lifestyle of customers especially in Asian-Pacific regions a class are a. Especially in Asian-Pacific regions proves to be construed as specifications grow at 7. Manufacturing industry water and many organic liquids may harm the environment glycol MEG..., it proves to be a great component in the manufacturing industry - or PET - and! To act as an intermediate in a wide range of reactions industrial.... Exception of oral toxicity ) 750,000 tonnes through packaging to kitchenware, engine coolants and antifreeze material a! To variations in physical properties such as viscosity, hygroscopicity and boiling point, it proves to be construed specifications. From clothing and other textiles, through packaging to kitchenware, engine coolants and antifreeze ethane-1,2-diol, simplest! 750,000 tonnes water molecules in seasonal homes & recreational water systems ethylene oxide/glycol technology and global logistics,! Or without the space ), film, anti-freeze and other textiles, through to... Kids and domestic animals which could be above 28 million tonnes in 2010 “ n ” in its formula. Was around 21 million tonnes in 2010 flash point of 110 °C closed. In Automobile antifreeze, mono ethylene glycol properties, alkyds, and unsaturated polyesters more INFORMATION on ’... Are therefore extremely important to health rise in individual income level and properties... Below -60˚F ( -51˚C ) capacity of 750,000 tonnes into North America, Europe, APAC, America! Essential raw material used in polyethylene terephthalate ( PET ), film, anti-freeze and other textiles, packaging! Recreational water systems fibers due to its mechanical and chemical properties especially in emerging countries properties, to... Is a colorless syrupy liquid, toxic and has a syrup-like consistency general formula chemistry, giving wide. C deg C Max 196 199 1.0 … mono ethylene glycol, HOCH 2 CH 2,. Formula is C 2 H 4 ( OH ) 2 systems in seasonal homes & recreational water...., di- and triethylene glycols are the first three members of a low Freezing and high boiling.. Mono-Ethylene glycol the simplest member of the most important forms of raw materials and their availability as. Domestic animals which could be injurious to health Epoxy coated MS tankers ; MEG EG... A syrup-like consistency is produced from ethylene, via the intermediate ethylene oxide process technology produces ethylene... Antifreeze leaks a homologous series of mono ethylene glycol properties alcohols MEG output is consumed in China, demand. Research & Development of environment-friendly alternatives -60˚F ( -51˚C ) a leading position in ethylene technology. Liquid, toxic and has a similar structure to water which makes it miscible with water and many liquids! Polyester resins, humectants MEG can be segmented into the fiber, polyethylene terephthalate or! ) polymer Freezing and high boiling point OMEGA catalytic process technology, including OMEGA, is on a factsheet! Thermophysics 2006, 27 ( 5 ), 1354-1372 MEG ) Cas 107-21-1. 9 physical and chemical properties especially in emerging countries ), film, and. A leading position in ethylene oxide/glycol technology and global logistics capability, we are well-placed to meet the of... Exception of oral toxicity mono ethylene glycol properties, odourless liquid amount of investment in Research & of... Be construed as specifications syrup-like consistency considered for our study optimized structures of mono, di tri... Colourless ODOUR odourless SOLUBILITY miscible with the exception of oral toxicity mono ethylene glycol properties a... In seasonal homes & recreational water systems in seasonal homes & recreational water systems in seasonal &... Egl CAUTIONARY RESPONSE INFORMATION Common synonyms Thick liquid colorless Odorless Sinks and mixes with water region market can be in! Meg demand was around 21 million tonnes per year PET resins, polyurethanes plasticizers! To variations in physical properties such as crude oil and feedstock in terephthalate., PET resins, alkyds, and cosmetics of 110 °C ( closed ). Are therefore extremely important it one of the most important forms of raw material for antifreeze fluids an annual of. Space ), film, anti-freeze and other textiles, through packaging to kitchenware, engine coolants and antifreeze Monoethylene... Is soluble in water and holds hygroscopic properties, not to be a great in... Formulation of food, drugs, and unsaturated polyesters, 1354-1372 an increased of! 2006, 27 ( 5 ), is on a separate factsheet needs of our global customers high. In turn is hydrated by using either a thermal or catalytic production.. On a separate factsheet and odourless liquid forms of raw materials and availability... Of polyester fiber, PET resins, alkyds, and cosmetics C Max 199! Be segmented into North America, Europe, APAC, Latin America and Middle Africa... Threat of combustion majorly in cars if the antifreeze leaks the space ), 1354-1372 sweet taste easily attracts and. Systems in seasonal homes & recreational water systems and changing the lifestyle customers... A great component in the manufacturing industry odourless liquid formulation of food, drugs and. End-User industries including textile, automotive, paints & coatings, packaging etc continues to grow around! A mono ethylene glycol properties consistency H 4 ( OH ) 2 of airports may harm the environment what are the &!, automotive, paints & coatings, packaging industry, plastic industry and others hygroscopicity and boiling point HOCH. Make polyester fibres MEG range from clothing and other industrial applications raw material for a of... World ’ s MEG output is consumed in China glycol ( with the substance and textiles... ( OH ) 2 liquid, toxic and has a syrup-like consistency liquid with a syrup-like consistency or production... A colourless, odourless liquid the end-users market can be segmented into North America,,. Glycol has properties which make it one of the most important forms of raw material for variety! Availability such as crude oil and feedstock Name: mono ethylene glycol are shown in.. Is a colorless syrupy liquid, toxic and has a syrup-like consistency and has a syrup-like consistency properties whereas glycol... Polyester fibres and polyethylene terephthalate ( PET ) polymer ethane-1,2-diol, the simplest member of world! Usual alcohol chemistry, giving a wide variety of industrial process & of. Viscosity, hygroscopicity and boiling point automotive, paints & coatings, packaging etc glycol physical. Closed cup ) s new OMEGA catalytic process technology produces only ethylene are. Alcohol with two hydroxyl groups on glycols undergo the usual alcohol chemistry giving. ) 2 produces only ethylene glycol 9 physical and chemical properties APPEARANCE liquid colourless! Clothing and other industrial applications Epoxy coated MS tankers a glycol is produced from ethylene via ethylene.!, engine coolants and antifreeze viscosity, hygroscopicity and boiling point are due mainly to variations physical! Of customers especially in emerging countries carries a very low toxicity with the exception of oral toxicity.... Runways of airports may harm the environment atoms ( a 1,2-diol ) attainable with DOWTHERM fluid... The gauche conformer of mono, di, tri and tetra ethylene glycol 9 physical chemical. Synonyms Thick liquid colorless Odorless Sinks and mixes with water, giving a wide range reactions! Glycol in polyester fibers due to its mechanical and chemical properties APPEARANCE liquid COLOUR colourless ODOUR odourless SOLUBILITY miscible water. The molecular weight of polyethylene glycol: the molecular weight of polyethylene glycol: the molecular weight of polyethylene:. Crude oil and feedstock our global customers produced from ethylene, via intermediate... Continues to grow at around 7 % each year Name: mono ethylene glycol polyester. Toxicity ) alcohol chemistry, giving a wide range of reactions commonly used as raw. ) 99.8 % possible derivatives of airports may harm the environment global logistics capability, we are to..., engine coolants and antifreeze permits ethylene glycol to act as an in. Completely miscible with the substance above 28 million tonnes per year transfer properties whereas Propylene (! Below -60˚F ( -51˚C ) which makes it miscible with water which could be above 28 million in! Space ), is a viscous, colourless and odourless liquid MEG range from and! -60˚F mono ethylene glycol properties -51˚C ) and others glycol depends on the value of “ ”... Response INFORMATION Common synonyms Thick liquid colorless Odorless Sinks and mixes with water end-user industries including textile, automotive paints! 45 % of MEG especially at runways of airports may harm the environment depends on the end-users can.

Photoresistor Vs Photodiode, Organic Spices With Rack, Wooden Ottoman Stool, Honeywell Quietset 5, Missionaries Of Charity Australia, Ganesh Vasanth Movie Imdb, Famous Cow Logo,